ライフサイエンスコーパス: copolymerization

1 ic acid is controlled by the degree of graft copolymerization.

2 period prior to reaching the maximum rate of copolymerization.

3 te Ti catalyst is the active species for the copolymerization.

4 (i.e., ionic or radical) cannot explain this copolymerization.

5 ates chain growth and precludes propylene/VC copolymerization.

6 s can be substituted for Zn and still effect copolymerization.

7 (2)]PdMe(THF), is active for CO and ethylene copolymerization.

8 s which may not be accessible through direct copolymerization.

9 zenium cations were selected to initiate the copolymerization.

10 the polymerization behavior of BisGMA/TEGDMA copolymerizations.

11 ion and possible side reactions; a dinuclear copolymerization active site is implicated.

12 zation, polar solvents are found to increase copolymerization activities and coproduce atactic polyst

13 The copolymerization activity and polyketone molecular weigh

14 the copolymerization behavior including the copolymerization activity, copolymer sequence distributi

15 zing chelating diphosphines (e.g., CO/alkene copolymerization and alkene hydroformylation) are consid

16 membranes (AEMs), which were synthesized by copolymerization and cross-linking of a norbornene monom

17 chemical properties of polymer scaffold via copolymerization and electrospinning techniques.

18 lenCo(III)X-catalyzed styrene oxide SO/CO(2) copolymerization and ring-opening polymerization of lact

19 t system leads to similar reaction rates for copolymerization and ROP and therefore to a terpolymer w

20 fully synthesized via NCA-based ring-opening copolymerization and their composition was confirmed by

21 evel (elemental doping) and molecular level (copolymerization), and (3) modification of g-C3N4 with w

22 s microtubule plus-ends by a preassociation, copolymerization, and regulated release mechanism.

23 further demonstrated the versatility of this copolymerization approach by synthesizing AB graft diblo

24 ions of these results for olefin/vinyl ether copolymerization are discussed.

25 ions (MWD approximately 1.1), indicating the copolymerizations are living.

26 red by a standard statistical description of copolymerization, are found to have a negligible influen

27 of functionalized monomers in Ziegler-Natta copolymerizations, are presented.

28 ts in remarkable activity enhancement of the copolymerization as well as improved stereoselectivity a

29 The BisGMA/TEGDMA copolymerization behaved similarly to other dimethacryla

30 substituent R and the bridge E influence the copolymerization behavior including the copolymerization

31 lid-state structures, solution dynamics, and copolymerization behavior with CO(2) and cyclohexene oxi

32 can be synthesized by a palladium catalyzed copolymerization between 9,10-dibromoanthracene and a va

33 The results indicate that copolymerization between a strong electron donor and wea

34 Here, the supramolecular copolymerization between two slightly structurally diffe

35 rs that govern the rROP mechanism; (iii) the copolymerization by conventional or controlled/living ra

36 Similarly, efficient one-pot diblock copolymerization by sequential addition of ethylene glyc

37 ning polymerization (ROP) of BBL and CHO/CO2 copolymerization by the presence of CO2 in the reaction

38 versatile high temperature ethylene-1-octene copolymerization capabilities of this catalyst class, an

39 The free-radical copolymerization characteristics of alpha-EIA and IEM we

40 Under ethylene/octene copolymerization conditions, a plurality of new catalyst

41 ue; this finding is seemingly independent of copolymerization conversion or reaction parameters.

42 study, determined that there is, however, no copolymerization detectable (i.e., that the synthesis an

43 lymerization conditions, rate studies on the copolymerization exhibit no dependence in [CO(2)], a fir

44 in which chain transfer agents are added to copolymerization experiments indicate that rapid chain t

45 osphate time-courses from polymerization and copolymerization experiments of ATP- and ADP-actin are s

46 + B1 and Ti1 + B1-mediated ethylene-styrene copolymerizations follow second-order Markovian statisti

47 sible addition-fragmentation chain transfer) copolymerization, followed by chain extension.

48 ering the bandgap (Eg), donor-acceptor (D-A) copolymerization for narrowing Eg and 2-dimensional conj

49 stry of the monomer and catalyst used in the copolymerization has dramatic effects on catalytic activ

50 Significant increases in the rate of copolymerization have been achieved with turnover freque

51 at modification of the proposed biosensor by copolymerization have provided to give perfect response

52 , to date, regioselective processes for this copolymerization have remained relatively unexplored.

53 ene + amino olefin [AO; H2 C=CH(CH2 )n NR2 ] copolymerizations in the absence of a Lewis-acidic maski

54 ent for epoxide and carbon dioxide/anhydride copolymerizations; in contrast, so far pure heterodinucl

55 Stoichiometric reactions of the copolymerization initiation steps show that zinc alkoxid

56 iffusion of two monomers and their oxidative copolymerization inside a solid-state gel electrolyte is

57 ched covalently to the solid support through copolymerization into acrylamide beads.

58 monitoring of the reactions, a mechanism of copolymerization is proposed where the neutral cocatalys

59 Although this copolymerization is well-studied using light microscopic

60 ure of the nanoparticles allowed for further copolymerization leading to multiresponsive nanostructur

61 nts also indicate that known noncoordination copolymerization mechanisms (i.e., ionic or radical) can

62 rent state of the field of epoxide/anhydride copolymerization mediated by discrete catalysts and the

63 The polymer is synthesized by template copolymerization methods and consists of a porous methac

64 ants were determined according to a terminal copolymerization model.

65 were performed on the perfectly alternating copolymerization of 1-butene oxide and carbic anhydride

66 r hydrophobicity as a monolith prepared from copolymerization of 2-acrylamido-2-methyl-1-propanesulfo

67 The organocatalytic anionic ring-opening copolymerization of 2-alkyl-2-oxo-1,3,2-dioxaphospholane

68 ustness of the method was highlighted in the copolymerization of a 256-membered ANNNN library compris

69 ial) derived from zinc-mediated coordination copolymerization of a dicarboxylic and tricarboxylic aci

70 n of hydrogel hydrophobicity from either the copolymerization of a hydrolyzable lactone ring or the h

71 Via solvothermal copolymerization of a monomeric ionic liquid and divinyl

72 ts (i.e., macroinitiators for a miniemulsion copolymerization of a monovinyl monomer and divinyl cros

73 nthesized semicrystalline polyesters via the copolymerization of a range of epoxide/anhydride monomer

74 to alkaline anion exchange membranes via the copolymerization of a tetraalkylammonium-functionalized

75 highly active, regioselective system for the copolymerization of a variety of terminal epoxides and c

76 thesized via inverse emulsion (water-in-oil) copolymerization of acrylamide and a low percentage (app

77 olecular polymer networks through an in situ copolymerization of acrylamide and functional monomers,

78 density that can be tailored by ring-opening copolymerization of alpha-propargyl-delta-valerolactone

79 t, modification of the proposed biosensor by copolymerization of amine functionalized monomer, which

80 temperature (LCST) were created through the copolymerization of an aminooxy-bearing methacrylamide w

81 One-pot copolymerization of an omega-norbornenyl macromonomer an

82 ant obstacles to insertion polymerization or copolymerization of AN using L(2)PdR+ catalysts are the

83 We further demonstrate that block copolymerization of betaMdeltaVL and lactide leads to a

84 le surface chemistries is easily achieved by copolymerization of butyl methacrylate with ethylene dim

85 The reaction kinetics of the copolymerization of carbon dioxide and cyclohexene oxide

86 nd regioslective copolymers derived from the copolymerization of carbonyl sulfide (COS) and epoxides

87 sition, whereas 40 bar CO2 affords exclusive copolymerization of CHO/CO2.

88 anation of the role of the cocatalyst in the copolymerization of CO2 and cyclohexene oxide catalyzed

89 Here, we show that copolymerization of collagen I with polyacrylamide produ

90 oly(propylene succinate) synthesized via the copolymerization of cyclic anhydrides and epoxides.

91 out compromising their crystallinity via the copolymerization of cyclic lactones with propargyl 3-met

92 highly active dimagnesium catalysts for the copolymerization of cyclohexene oxide and carbon dioxide

93 The mechanism of the copolymerization of cyclohexene oxide and carbon dioxide

94 Furthermore, copolymerization of cyclopentene oxide (CPO) and CO2 was

95 ith pendant functionalities via ring-opening copolymerization of delta-valerolactone with alpha-allyl

96 Copolymerization of DPP with DPP yields a copolymer with

97 to -12) have been synthesized as crystals by copolymerization of either Zn(II) (ZIF-1 to -4, -6 to -8

98 sable polymeric materials through the direct copolymerization of elemental sulfur with vinylic monome

99 istence of activated NMII monomers in cells, copolymerization of endogenous NMIIA and NMIIB molecules

100 EG (mf-PEG) and PPO structures accessible by copolymerization of EO or PO with functional epoxide com

101 highly active catalysts for the alternating copolymerization of epoxides and CO2.

102 lyesters synthesized through the alternating copolymerization of epoxides and cyclic anhydrides compo

103 sized for the first time through the anionic copolymerization of epoxides with CO2, under metal-free

104 m catalysts for the ring-opening alternating copolymerization of epoxides with cyclic anhydrides.

105 polymerization of lactones and ring-opening copolymerization of epoxides/anhydrides.

106 tios (r1, r2) for the free-radical-initiated copolymerization of ethyl alpha-isocyanatoacrylate (alph

107 The copolymerization of ethylene and 1-hexene at 40 degreesC

108 A detailed mechanistic investigation of the copolymerization of ethylene and methyl acrylate (MA) by

109 The copolymerization of ethylene and propylene with bridged

110 time commercially relevant catalysts for the copolymerization of ethylene and styrene have been ident

111 es the homopolymerization of styrene and the copolymerization of ethylene and styrenic comonomers med

112 formation of polyethylene from ethylene, and copolymerization of ethylene with 1-octene.

113 Direct coordinative copolymerization of ethylene with functionalized co-mono

114 or the first time successfully controlled by copolymerization of ethylene with polar olefins using a

115 Heparan sulfate formation occurs by the copolymerization of glucuronic acid (GlcA) and N-acetylg

116 Simultaneous copolymerization of green fluorescing dCTP and dUTP nucl

117 coatings via ultraviolet (UV) photoinitiated copolymerization of ionic liquid (IL) monomers on a fuse

118 lymers were synthesized via enzyme-catalyzed copolymerization of lactone with dialkyl diester and ami

119 phasis is on homopolymerization, but related copolymerization of less activated monomers is mentioned

120 ing mesochlorin e6 (Mce6) was synthesized by copolymerization of MA-Fab', HPMA, and MA-GFLG-Mce6.

121 rotaxanes via ring-opening olefin metathesis copolymerization of macrocycles and metalated [2]catenan

122 The ring-opening copolymerization of maleic anhydride and propylene oxide

123 We report the ring-opening copolymerization of maleic anhydride with a variety of e

124 The pCQ polymers were synthesized by copolymerization of methacryloylated hydroxy-CQ (HCQ) an

125 ica capillaries in a single step by a simple copolymerization of mixtures of butyl methacrylate, ethy

126 ica capillaries in a single step by a simple copolymerization of mixtures of O-[2-(methacryloyloxy)et

127 conditions, this catalyst also mediates the copolymerization of MMA + styrene (1:19 ratio) at 50 deg

128 The copolymerization of monocationic and dicationic IL cross

129 The statistical copolymerization of MTEGE with ethylene oxide results in

130 lung abnormalities of Tsk/+ mice are due to copolymerization of mutant and wild-type molecules into

131 witterionic monolith was prepared by thermal copolymerization of N,N-dimethyl-N-methacryloxyethyl-N-(

132 We show that copolymerization of NMIIA and NMIIB followed by their di

133 (BDI)Zn-1 also enables controlled copolymerization of OCAs and lactide, facilitating the s

134 ylammonium silanolate-initiated ring-opening copolymerization of octamethylcyclotetrasiloxane (D(4))

135 hylene carbonate and 107.6 kJ x mol (-1) for copolymerization of oxetane and carbon dioxide supports

136 re prepared with comb-like structure by RAFT copolymerization of peptide macromonomers with N-(2-hydr

137 polar functional groups and the block/graft copolymerization of PHAs with hydrophilic components in

138 resonance spectroscopy of products from the copolymerization of piceatannol and monolignols confirms

139 Alkyne-containing beads prepared by direct copolymerization of propargyl acrylate with ethylene dim

140 active catalysts for the living, alternating copolymerization of propylene oxide (PO) and CO(2), yiel

141 Just add water: The copolymerization of propylene oxide and CO2 catalyzed by

142 The alternating copolymerization of propylene oxide with terpene-based c

143 ilaments similar to the structures formed by copolymerization of purified Y53A-actin and wild-type ac

144 arbonate)s are obtained via the ring-opening copolymerization of rac-/(R)-benzyl glycidate with CO2 u

145 rbonate)s were obtained via the ring-opening copolymerization of rac-/(R)-benzyl glycidyl ether with

146 f 620 turnovers per hour is achieved for the copolymerization of rac-PO and CO(2), yielding iso-enric

147 Copolymerization of racemic alpha-olefins with ethylene

148 ne backbone linkages can be synthesized from copolymerization of readily accessible aryl dibromides a

149 composite hydrogel particles are prepared by copolymerization of sodium acrylate and N-isopropylacryl

150 ca capillaries, by thermally induced in situ copolymerization of styrene and divinylbenzene.

151 lymers were prepared by a controlled radical copolymerization of styrene with designer boron or phosp

152 sors were synthesized by sequence-controlled copolymerization of styrene with N-substituted maleimide

153 MS(2) data provided conclusive evidence that copolymerization of styrene/DMSS mixtures leads to chain

154 One was prepared from the copolymerization of sulfoethyl methacrylate and poly(eth

155 n vesicle-templated nanocapsules prepared by copolymerization of tert-butyl methacrylate, butyl metha

156 The copolymerization of the chiral binaphthyl monomer with t

157 The copolymerization of the eight membered monomers with 6-m

158 s were induced by binding of Fab(1-7) and by copolymerization of the ErIA-labeled actin monomers with

159 Immobilization occurs via photoinitiated copolymerization of the indicator with acrylamide on the

160 targeted systems can be directly prepared by copolymerization of the MA-Fab', N-(2-hydroxypropyl)meth

161 It was prepared by copolymerization of the PEG-trypsin-aprotinin complex du

162 One-pot copolymerization of the two monomers to give block copol

163 s-ends, an observation inconsistent with the copolymerization of this complex with tubulin for plus-e

164 ion side reactions at high conversion in the copolymerization of tricyclic anhydrides with excess pro

165 Additionally, copolymerization of Tsk fibrillin 1 with wild-type fibri

166 contrast, when microtubules are generated by copolymerization of tubulin and tau, a distinct populati

167 ss reminiscent of a living covalent gradient copolymerization of two different monomers.

168 gies used thus far have relied on the random copolymerization of two electronically distinct molecula

169 Keratin filaments arise from the copolymerization of type I and II sequences, and form a

170 to metal-catalyzed insertion polymerization/copolymerization of VC.

171 The copolymerizations of CHO (1.98 M in toluene) and 300 psi

172 Copolymerizations of cyclohexene oxide (CHO) and CO2 wit

173 Copolymerizations of ethylene with vinyltrialkoxysilanes

174 Copolymerizations of ethylene with vinyltrialkoxysilanes

175 hydrophobicity of the polymer through random copolymerizations of modular norbornene derivatives, hig

176 complex architectures were achieved through copolymerizations of selected diluents with a poly(d,l-l

177 ertive stereoregular homopolymerizations and copolymerizations of styrene and methyl methacrylate (MM

178 gest that the coexpression, and probably the copolymerization, of the abundant ACT7 with the other ac

179 Conventional one gallon batch reactor copolymerizations performed using selected amide-ether h

180 nt strategies, including surface coating and copolymerization/physical blending, necessitate compromi

181 For ethylene-styrene copolymerization, polar solvents are found to increase c

182 tant/HbS hybrid was found to be 6.2, and the copolymerization probability for the triple mutant/HbS h

183 Relative to HbS, the copolymerization probability of the quadruple mutant/HbS

184 c cycles is proposed wherein the alternating copolymerization proceeds via intermediates that have ca

185 echanistic differences in the supramolecular copolymerization process is investigated as a function o

186 nd different species start to coexist in the copolymerization process.

187 ment in homogenous olefin polymerization and copolymerization processes.

188 )B(C(6)F(5))(2) (BN(2)) in ethylene + olefin copolymerization processes.

189 ts comparable to those produced using Stille copolymerization protocols.

190 OMP mechanism, monomer design, and homo- and copolymerization rate trends offer a general strategy fo

191 able a mechanism to be proposed for both the copolymerization reaction and possible side reactions; a

192 In these latter cases the copolymerization reaction exhibits ideal kinetic behavio

193 The working mechanistic model for the copolymerization reaction involves first aziridine inser

194 nd infrared spectroscopy, a mechanism of the copolymerization reaction is proposed.

195 mably is true for the initiation step of the copolymerization reaction, the rate of carbonate chain g

196 Conducting copolymerization reactions in the presence of both monom

197 ene oxide and exo-2,3-epoxynorbornane toward copolymerization reactions with carbon dioxide, in the p

198 Both homopolymerization and copolymerization results argue that substantial cooperat

199 lines of evidence from both homo- and block copolymerization results have demonstrated living charac

200 al conjugate addition steps to explain these copolymerization results.

201 erization (ROP) of lactones and ring-opening copolymerization (ROCOP) of epoxides, anhydrides, and CO

202 Cyclopolymerization and ethylene/propylene copolymerization strategies are employed to support this

203 Results from propylene copolymerizations suggested that chain end control arisi

204 The advantages of such a copolymerization system are manifold: (i) no need for mu

205 Controlled copolymerization therefore expands the parameter space f

206 In ethylene copolymerization, Ti(2) + BN(2) enchains approximately 2

207 In ethylene copolymerization, Ti2 + B1 enchains 15.4% more styrene (

208 onomers and mediates efficient homo or block copolymerization to generate hydrophilic polymers with c

209 end of the salenCo(III)X-catalyzed SO/CO(2) copolymerization to in situ generate hydroxyl groups at

210 e at or above the critical concentration for copolymerization to occur, indicating that FtsZ is nucle

211 In catalytic copolymerization, undesired chain transfer after incorpo

212 4%) in comparison with EBICGCTi2Me4-mediated copolymerizations (up to 32%).

213 re consistently higher for CGCTiMe2-mediated copolymerizations (up to 54%) in comparison with EBICGCT

214 lity is further exemplified by in situ block copolymerization upon sequential monomer addition for th

215 pon the kinetic analysis of ethylene-styrene copolymerization using constrained geometry catalyst (et

216 um i.d. capillaries by one-step UV-initiated copolymerization using methanol and ethyl ether as porog

217 rtin-Hammett kinetic behavior as observed in copolymerization using the normal Brookhart type of Pd(I

218 nusually high incorporations of acrylates in copolymerization using this catalyst prompted us to cond

219 extensions to full conversion or multiblock copolymerization via iterative monomer addition after fu

220 ne and acrylonitrile, both cycloaddition and copolymerization were observed experimentally; these tre

221 duct a full mechanistic study on ethylene/MA copolymerization, which indicates a dramatic departure f

222 Polymerization of EDOT-PdBPI and copolymerization with 4-amino-N-(2,5-di(thiophene-2-yl)-

223 is monomer enables a room temperature Suzuki copolymerization with a diketopyrrolopyrrole comonomer t

224 crylic-functionalized glass surfaces through copolymerization with acrylic monomer.

225 containing the C terminus were competent for copolymerization with capsid subunits into procapsid she

226 ucing biocompatible polymers via alternating copolymerization with carbon dioxide.

227 The rac-PO/CO(2) copolymerization with catalyst rac-(salcy)CoBr yields sy

228 conductors are synthesized by end-capping or copolymerization with dithienothiophen-2-yl units.

229 Copolymerization with ethyl acrylate is also possible.

230 Copolymerization with Mal3 favors 13 protofilament micro

231 nsoluble product, [NH(2)-BH(2)](n) (8d), but copolymerization with MeNH(2).BH(3) gave soluble random

232 Ethylene/propylene copolymerization with metallocenes having heterotopic ac

233 the first seven N-terminal residues and (2) copolymerization with monomers treated with the zero-len

234 methacrylamide) nanogels were synthesized by copolymerization with N,O-(dimethacryloyl) hydroxylamine

235 Structural integrity is provided by copolymerization with tetraethoxysilane, which produces

236 s by phalloidin and improved greatly through copolymerization with the wild-type actin.

237 Copolymerization with thiophene afforded a polymer with

238 Copolymerization with thiophene resulted in a semicrysta

239 olymerization incompetent, the impact of its copolymerization with unlabeled actin on filament struct

240 a 75-microm-i.d. capillary by photoinitiated copolymerization with water, methanol, and ethyl ether a

241 Both defects are attenuated by copolymerization with WT.

242 nalized (AA-type) monomers in Suzuki-Miyaura copolymerizations with dibromo-heteroarenes (BB-type mon

243 FI(2)-Ni(2)-catalyzed copolymerizations with ethylene + methylacrylate or meth

244 FI(2)-Ni(2)-mediated copolymerizations with ethylene + polar-functionalized n

245 Copolymerizations with ethylene revealed that the polyme

246 or the behavior of VA and VA(f) in attempted copolymerizations with ethylene.

247 monomers, RAFT-mediated radical ring-opening copolymerizations with traditional vinyl monomers such a

248 complex exhibits exceptional selectivity for copolymerization without transesterification or epimeriz

249 found to be incompetent for ethylene-styrene copolymerization, yielding only mixtures of polyethylene