ライフサイエンスコーパス: polyoxometalate

1 blackberry formation for a non-Mo-containing polyoxometalate.

2 now facilitate efforts to design functional polyoxometalates.

3 sport studies of magnetically functionalized polyoxometalates.

4 of molecular oxygen in reactions mediated by polyoxometalates.

5 {P2 W18 } (3), and {Mo12 O36 (HPO3 )2 } (4) polyoxometalates.

6 ns, flexibility and dynamic is possible with polyoxometalates.

7 Finally, inhibition of CD39 activity by polyoxometalate-1, a pharmacologic inhibitor of nucleosi

8 (31)P NMR shows that the Cu-NO2-substituted polyoxometalates act as oxygen donors to the C-C double

9 hesized gold nanoparticles (AuNPs) and alpha-polyoxometalate (alpha-POM) (K7PMO2W9O39 .

10 but less common than other Keggin isomers in polyoxometalate and polyoxocation chemistry.

11 r the screening and scale up of syntheses of polyoxometalates and manganese-based single-molecule mag

12 the process of the self-assembly of gigantic polyoxometalates and their subsequent molecular growth,

13 l and biological sciences, are a subclass of polyoxometalates and usually self-assemble in aqueous-ph

14 table redox states (e.g., metalloporphyrins, polyoxometalates, and C60) is more particularly discusse

15 clude aluminum polycations, transition-metal polyoxometalates, and the actinyl peroxide clusters have

16 2)Mo(18)O(62)](4-), and [S(2)W(18)O(62)](4-) polyoxometalate anions (POMs) and oxidation of water occ

17 including but not limited to combinations of polyoxometalate anions and redox-active cations, was con

18 Unlike metallo-organic catalysts, polyoxometalate anions are oxidatively stable and are re

19 show that equilibration reactions typical of polyoxometalate anions keep the pH of the system near 7

20 Polyoxometalates are anionic metal oxide clusters of a v

21 Polyoxometalates are clusters of metal-oxide units, comp

22 The fuel cell uses polyoxometalates as the photocatalyst and charge carrier

23 to describe the synthesis of the core-shell polyoxometalates based on the monitoring results.

24 Two MOF-like but all-inorganic polyoxometalate-based networks, [Na7X2W18Sn9Cl5O68.(H2O)

25 Polyoxometalate-based open frameworks (POM-OFs) are exte

26 Meanwhile, polyoxometalates-based organic-inorganic hybrid material

27 Ru4-polyoxometalate bridges the gap between homogeneous and

28 o(2)O(2)S(2)}(2+) and {Mo(3)S(4)}(4+) toward polyoxometalate building blocks.

29 porating phosphorus(III)-based anions into a polyoxometalate cage, a new type of tungsten-based uncon

30 The reduced polyoxometalate can be reoxidized in fuel cells that con

31 A typical type of core-shell polyoxometalates can be obtained through the Keggin-type

32 we describe how building block libraries of polyoxometalates can be used to construct systems with i

33 In a similar vein, polyoxometalates can stabilize metal nanoparticles, lead

34 chemical warfare nerve agent simulant over a polyoxometalate catalyst.

35 munication describes a new method for the Pd/polyoxometalate-catalyzed aerobic olefination of unactiv

36 Polyoxometalate cluster anions (POMs) control formation

37 elope of both events and employ it for a new polyoxometalate cluster, Na6 [Mo120 Ce6 O366 H12 (H2 O)7

38 amolecular assembly of a series of nanoscale polyoxometalate clusters (from the same one-pot reaction

39 Uranyl polyoxometalate clusters are both fundamentally fascinat

40 nd have many common building blocks; in fact polyoxometalate clusters are perhaps the largest non-bio

41 hods for the grafting of peptide chains onto polyoxometalate clusters by the use of general activated

42 d to probe the mechanism of self-assembly of polyoxometalate clusters in solution.

43 lecular nanostructures like coordination and polyoxometalate clusters is extremely time-consuming sin

44 Despite the vast number of polyoxometalate clusters now known, an ongoing and impor

45 zeolitic channels and on stronger acids HPW (polyoxometalate clusters on silica).

46 Mn-Anderson based polyoxometalate clusters with different terminal groups

47 rometer-scale tubes and membranes built from polyoxometalate clusters.

48 Nanostructured inverse hexagonal polyoxometalate composite films were cast directly from

49 ns to produce an aqueous solution of reduced polyoxometalate compounds that can be used to generate p

50 Herein, using the polyoxometalate H(3)PMo(1)(2)O(4)(0), we introduce the c

51 as an active catalyst, and iron(II) and the polyoxometalate H(5)PMo(10)V(2)O(40) (POM-V2) were ident

52 A well-defined alpha-Keggin polyoxometalate, H(5)PV(2)Mo(10)O(40), can be viewed as

53 at all structural sites in two isostructural polyoxometalates, [H(x)Nb(10)O(28)]((6-x)-) and [H(x)Ti(

54 The polyoxometalate H5PV2Mo10O40 mediates the insertion of a

55 molecular water oxidation catalysts based on polyoxometalates have been reported that combine the adv

56 A series of polyoxometalates have been synthesized and evaluated for

57 Not only can polyoxometalates have gigantic nanoscale molecular struc

58 talyst development, and the possible uses of polyoxometalates in green energy science.

59 hould aid in the exploitation of these giant polyoxometalates in solution for various applications.

60 None of the polyoxometalates inhibited the binding of a specific CXC

61 enerally applicable strategy for integrating polyoxometalates into functional architectures and devic

62 Polyoxometalate ions (POMs) have structures similar to c

63 nd composition suggests reaction pathways in polyoxometalate ions will be highly variable even within

64 ared by pretreatment of the aqua-coordinated polyoxometalates (L = H2O) with NO2 or are formed in sit

65 based on redox-active (vanadate(V)-centered) polyoxometalate ligands, Na10[Co4(H2O)2(VW9O34)2].35H2O

66 c hybrid molecule comprising two Dawson-type polyoxometalates linked by a 2,2'-bipyridine unit, which

67 very similar to the unique self-assembly of polyoxometalate macroanions into single-layer, spherical

68 onstruct complex chemical systems based upon polyoxometalates, manipulating the templating/self templ

69 demonstrating the crucial role played by the polyoxometalate metal oxide cluster as an intermediary i

70 g a terminal aromatic pyrene platform with a polyoxometalate Mn-Anderson cluster as linker, demonstra

71 a nanoscale anion, the tetragonal Lindqvist polyoxometalate Mo6O19(2-).

72 been achieved using the ruthenium-containing polyoxometalate molecular catalyst, [{Ru4O4(OH)2(H2O)4}(

73 Here we show that a molybdenum(VI) oxide 'polyoxometalate' molecular nanocluster containing two em

74 Niobium polyoxometalates (Nb-POMs) are unique in the aqueous met

75 inorganic hybrid complexes between CB[n] and polyoxometalates not only display a surprisingly high st

76 noted L) and the trivacant [AsW(9)O(33)](9-) polyoxometalate (noted POM) has been investigated.

77 ptor anion, alpha-SiV(V)W(11)O(40)(5-) (1, a polyoxometalate of the Keggin structural class), was use

78 Herein, we report a hybrid polyoxometalate organic-inorganic compound, Na2 [(HGMP)2

79 and programmed assembly of a dumbbell-shaped polyoxometalate-organic hybrid molecule comprising two D

80 with a 100% theoretical atom economy using a polyoxometalate oxygen donor has been found.

81 fter as (COD)Ir.POM(8-), where POM(9-) = the polyoxometalate, P2W15Nb3O62(9-)) under H2 is investigat

82 The polyoxometalate phosphotungstic acid has been used to se

83 een applied to the study of the reduction of polyoxometalate [PMo12O40](3-) adsorbed at a boron doped

84 imentally elusive delta-isomer of the Keggin polyoxometalate polyanion.

85 ed, dimeric, ZrIV-substituted Lindqvist-type polyoxometalate (POM) (nBu4N)6[{(mu-MeO)ZrW5O18}2], (TBA

86 report the encapsulation of a Ni-containing polyoxometalate (POM) [Ni4 (H2 O)2 (PW9 O34 )2 ](10-) (N

87 f pure approximately 0.75 nm size molybdenum polyoxometalate (POM) anions on 25 mug ( approximately 0

88 SS), [60]fullerene (C60), and Lindqvist-type polyoxometalate (POM) are used as building blocks to con

89 In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical Re

90 In this review we discuss the relevance of polyoxometalate (POM) chemistry to provide model objects

91 In the wide area of polyoxometalate (POM) chemistry, diphosphate/diphosphona

92 hybrid molecules containing a large anionic polyoxometalate (POM) cluster and two C6 and C16 alkyl c

93 nteract with the conjugate anion in W and Mo polyoxometalate (POM) clusters and gaseous mineral acids

94 Acid strengths for Keggin polyoxometalate (POM) clusters and zeolites, chosen beca

95 eactions on Bronsted acid catalysts based on polyoxometalate (POM) clusters are described in terms of

96 he contribution of building blocks of Keggin polyoxometalate (POM) clusters to redox processes are ch

97 a representative series of Keggin and Dawson polyoxometalate (POM) films in contact with a metallic (

98 lay an important structure-directing role in polyoxometalate (POM) growth in solution.

99 >30 coordination polymers incorporating this polyoxometalate (POM) ligand.

100 al core is stabilized by coordination of two polyoxometalate (POM) ligands.

101 Here we show that core-shell polyoxometalate (POM) molecules can act as candidate sto

102 ance fuel cells that are catalyzed solely by polyoxometalate (POM) solution without any solid metal o

103 Polyoxometalate (POM) species-nanoscale inorganic anions

104 self-assembly of hydrophilic Keplerate-type polyoxometalate (POM) {Mo(72)Fe(30)} macroanions into si

105 anion size and charge allows the Keggin-type polyoxometalate (POM), [CuPW(11)O(39)](5-), a catalyst f

106 ecognition processes involving a Dawson-type polyoxometalate (POM), [P2W18O62](6-), a cationic electr

107 This strategy employs a single material, a polyoxometalate (POM), alpha(2)-[P(2)W(17)O(61)](10-), t

108 osmotically driven crystal morphogenesis of polyoxometalate (POM)-based crystals is investigated, wh

109 driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing remote terpyr

110 Wells-Dawson [alpha(2)-P(2)W(17)O(61)](10-) polyoxometalate (POM)-supported [Re(CO)(3)](+) complex c

111 ocation process of countercations around one polyoxometalate(POM)-organic hybrid anionic cluster at v

112 Polyoxometalates (POMs) are discrete clusters of redox-a

113 POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-t

114 We report here that some polyoxometalates (POMs) favor polymerization of PrP 27-3

115 Polyoxometalates (POMs) have remarkable properties and a

116 Nb-containing polyoxometalates (POMs) of the Wells-Dawson class inhibi

117 of mononuclear lanthanoid complexes based on polyoxometalates (POMs) that exhibit single-molecule mag

118 peroxoniobium compounds to the corresponding polyoxometalates (POMs), alpha(1)-K(7)[P(2)W(17)NbO(62)]

119 , enzymes, ...) and inorganic molecules like polyoxometalates (POMs), which have very interesting app

120 Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymm

121 catalyst hypothesis: (i) six vanadium-based polyoxometalate precatalysts, (n-Bu4N)4H5PV14O42, (n-Bu4

122 The polyoxometalates represent a class of polyanionic compou

123 These redox reactions of polyoxometalates require protons, and thus such complexe

124 spinning NMR spectroscopy of six-coordinated polyoxometalate solids.

125 of 10-20 nm by post-process immersion into a polyoxometalate solution (phosphomolybdic acid, PMA) in

126 Here we investigate a nano-sized Ru4-polyoxometalate standing as an efficient artificial cata

127 rected assembly of a ring-shaped macrocyclic polyoxometalate structural building unit, {P(8)W(48)O(18

128 ew method to identify metallic nanoclusters (polyoxometalate structures) in solution at the single mo

129 ation to minimize steric clashes between the polyoxometalate subunits, in order to stabilize the corr

130 Recently we showed that V-containing polyoxometalates such as (n-Bu4N)7SiW9V3O40 or (n-Bu4N)9

131 s, is described using copper(II)-substituted polyoxometalates, such as {alpha2-Cu(L)P2W17O61}(8-) or

132 nner and outer faces of the gamma-CD for the polyoxometalate surfaces.

133 ates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical

134 in the reaction mechanism by protonating the polyoxometalate thereby enabling the activation of the m

135 where oxygen atoms are transferred from the polyoxometalate to the substrate.

136 id growth of tubes occurs from crystals of a polyoxometalate upon addition of an aqueous solution con

137 999, a catechol dioxygenase derived from a V-polyoxometalate was reported which was able to perform a

138 hat SMOF-1 adsorbs anionic Wells-Dawson-type polyoxometalates (WD-POMs) in a one-cage-one-guest manne

139 and water activation on multi-Ru-substituted polyoxometalates were studied using the B3LYP density fu

140 u(+) and Bu3Sn(+) cations coordinated to the polyoxometalate, which were also identified by ESI-MS.

141 y of ([UO2(O2)OH]60)(60-) (U60), an actinide polyoxometalate with fullerene topology, can be induced

142 The technique allows the measurement of polyoxometalates with over 2 orders of magnitude lower a

143 self-assembly of an equilibrated ensemble of polyoxometalates, with the heteropolytungstate anion [AI