ライフサイエンスコーパス: sacrificial

1 tolysis of reduced beef bc(1), Ru(2)D, and a sacrificial acceptor resulted in oxidation of cytochrome

2 toreforming of methanol, employed as a model sacrificial agent, on platinized samples resulted in hig

3 ers include presence or absence of (organic) sacrificial agents, applied pH, presence or absence of a

4 drogen donation from the reactant alcohol or sacrificial alcohol (i-PrOH).

5 oved by 2-norbornene, in contrast with other sacrificial alkenes.

6 waters by electrochemical treatment using a sacrificial aluminum anode was evaluated.

7 that of their mention as anatomic organs of sacrificial animals burned at the altar.

8 Reduction or deprotonation of the sacrificial anion forms insoluble byproducts and AdzH(+)

9 etween Na and AdzH(+)X(-) in which X(-) is a sacrificial anion such as glycolate, isethionate, or nit

10 vanostatic conditions using an aluminum wire sacrificial anode (seATRP) immersed directly into the re

11 It was hypothesized that the metals acted in sacrificial anode redox fashion to reduce or eliminate d

12 0 times more hydrogen (H2) from water heater sacrificial anode rods than does presence of copper dose

13 oncentrations in the microenvironment of the sacrificial anode where coagulant precursors are dissolv

14 uggest that lysine serves predominantly as a sacrificial antioxidant (via formation of lysine nitrile

15 ants and supports its hypothesized role as a sacrificial antioxidant.

16 -bound surfactants are carbonized in situ as sacrificial architectures that form a conformal coating

17 ate these more basic RTAs, the addition of a sacrificial base leads to efficacies that are unpreceden

18 heaters to convert light energy into heat, a sacrificial block copolymer surfactant to generate mesop

19 carbon, i.e., polyacrylonitrile (PAN), and a sacrificial block, i.e., poly(n-butyl acrylate) (PBA).

20 Here we present evidence for how this sacrificial bond and hidden length mechanism contributes

21 We envision that this straightforward sacrificial bonding strategy can be employed to improve

22 Sacrificial bonds and hidden length in structural molecu

23 ost-guest interactions can be dissociated as sacrificial bonds and their facile reformation results i

24 nterfacial soft layers that can also provide sacrificial bonds for self-repair.

25 We suggest that the sacrificial bonds found within or between collagen molec

26 In many biological cases, the breaking of sacrificial bonds has been found to be reversible, there

27 As in the case of the sacrificial bonds in single molecules, the effectiveness

28 hat on the molecular level, calcium-mediated sacrificial bonds increased stiffness and enhanced energ

29 Here, we show that incorporation of sacrificial bonds into a self-repairable network dramati

30 We propose that sacrificial bonds significantly influence the tendon fib

31 The time needed for these sacrificial bonds to reform after pulling correlates wit

32 like abalone nacre, contains polymers with 'sacrificial bonds' that both protect the polymer backbon

33 om Araneus has revealed rupture peaks due to sacrificial bonds, characteristic of other self-healing

34 In this work we propose various types of sacrificial bonds, their combination, and how they appea

35 leased by the breaking of weak bonds, called sacrificial bonds.

36 en microcapsules were created by coating the sacrificial CaCO3 using layer-by-layer technique.

37 ion losses, and the addition of glucose as a sacrificial carbon source helped minimize oxidation loss

38 n of fully cyclized GNRs induces cleavage of sacrificial carbonyl groups, resulting in atomically wel

39 For instance, zinc galvanizing provides sacrificial cathodic protection and acts as a barrier, b

40 beyond the traditional roles of barrier and sacrificial cathodic protection using a metal coating.

41 release in addition to barrier function and sacrificial cathodic protection.

42 process toward cesium ions and the use of a sacrificial cation exchanger (NaBPh(4)) to control loss

43 so far been studied almost exclusively with sacrificial chemical oxidants.

44 1.9 x 10(4) s(-1)cell(-1) without the use of sacrificial chemical reagents or carbon feedstocks other

45 erfusable microfluidic channels by embedding sacrificial circular gelatin vascular templates in colla

46 The coassembly of a sacrificial colloidal template with a matrix material av

47 ilms enabled by light-induced degradation of sacrificial compartments are introduced.

48 polymers containing polylactide (PLA) as the sacrificial component and perfectly linear polyethylene

49 Selective removal of the sacrificial component can leave a scaffold with well-con

50 Block polymers containing a sacrificial component have proven to be attractive precu

51 n, then the mixture was circulated through a sacrificial core.

52 es by two single-turnover reactions in which sacrificial desulfurization of LarE converts its conserv

53 Specially designed sacrificial dies heat the pre-compacted SiC powder speci

54 te residue Cys38 of N-Ada converts it from a sacrificial DNA repair protein to an enzyme that uses me

55 yrene in the presence of visible light and a sacrificial donor (ascorbate).

56 ored the effects of the CdS:CaI molar ratio, sacrificial donor concentration, and light intensity on

57 uction catalyst and N,N-dimethyl-p-toluidine sacrificial donor in 1:1 H2O:CH3CN, this Cu(I) sensitize

58 rom a molecular catalyst in the absence of a sacrificial donor reagent.

59 optimization with ascorbic acid present as a sacrificial donor resulted in photon-to-H(2) efficiencie

60 taining beef cytochrome bc(1), Ru(2)D, and a sacrificial donor resulted in reduction of cytochrome c(

61 of the targets hinders the diffusion of the sacrificial donor, inducing thus a photocurrent decrease

62 oves the photo-induced reduction step with a sacrificial donor, is used for validation of the propose

63 tly enhanced ( approximately 5 times) when a sacrificial donor, such as EDTA, is introduced into the

64 When electrons are supplied by a sacrificial donor, this technology forms the cathode of

65 r illumination and only in the presence of a sacrificial donor.

66 the photosensitizer and ascorbic acid as the sacrificial donor.

67 a species that persists in the presence of a sacrificial donor.

68 s thus observed directly in solution with no sacrificial donors or applied bias.

69 nts from a renewable source rather than from sacrificial donors.

70 an electrochemical system with mild steel as sacrificial electrodes to in-situ generate high strength

71 ficiency of a benchtop EC unit with aluminum sacrificial electrodes to reduce concentrations of the a

72 [Ru(II)(bpy)3](2+) as photosensitizer and a sacrificial electron acceptor (Na2S2O8).

73 containing reduced cyt bc(1), Ru(2)D, and a sacrificial electron acceptor results in oxidation of cy

74 Sodium persulfate acts as a sacrificial electron acceptor to oxidize the photosensit

75 2+) as a photosensitizer and persulfate as a sacrificial electron acceptor, 1-V2 exhibits higher sele

76 otosensitizer, [Ru(bpy)(3)](2+); and (iii) a sacrificial electron acceptor, S(2)O(8)(2-).

77 sfer to methylviologen, fast hole removal by sacrificial electron donor and slow charge recombination

78 e Ru(II*) of Ru2Z is reduced to Ru(I) by the sacrificial electron donor aniline, and Ru(I) then reduc

79 hexyl viologen dication in the presence of a sacrificial electron donor in an electron-pooling experi

80 miquinone generated by photoreduction from a sacrificial electron donor in solution was examined betw

81 The addition of EDTA as a sacrificial electron donor to the electrolyte resulted i

82 dy state illumination in the presence of the sacrificial electron donor triethylamine leads to the ap

83 -driven H(2) production in the presence of a sacrificial electron donor with an efficiency of 4%, whi

84 reduce hexyl-viologen dication (HV2+) and a sacrificial electron donor, 1-benzyl-1,4-dihydronicotina

85 In a Pt(II) chloro system that contains a sacrificial electron donor, either MeOH or triethanolami

86 er with [Ru(bpy)3]Cl2 and ascorbic acid as a sacrificial electron donor, in the presence of blue ligh

87 hotosensitizer and triethanolamine (TEOA) as sacrificial electron donor, the noble-metal-free complex

88 nsitizer (PS) and triethylamine (TEA) as the sacrificial electron donor, these complexes exhibit acti

89 tochemical CO(2) reduction is the need for a sacrificial electron donor, usually a tertiary amine.

90 of hydrogen from water in the presence of a sacrificial electron donor, without the apparent need fo

91 u(bpy)(3)]Cl(2) with sodium ascorbate as the sacrificial electron donor.

92 ge separator and mercaptopropionic acid as a sacrificial electron donor.

93 ox catalyst and N,N-diisopropylethylamine as sacrificial electron donor.

94 with sensitivity toward both H(2)ase and the sacrificial electron donor.

95 ) per QD in 10 h, using triethanolamine as a sacrificial electron donor.

96 ence from the excited PS was quenched by the sacrificial electron donor.

97 ) as the catalyst and triethanolamine as the sacrificial electron donor.

98 thylformamide with triethanolamine (TEOA) as sacrificial electron donor.

99 for hydrogen production in the presence of a sacrificial electron donor.

100 a molecular cobalt catalyst and vitamin C as sacrificial electron donor.

101 ulting from the Ba doping serve as effective sacrificial electron donors (SEDs) to scavenge the holes

102 f a molecular catalyst but avoids the use of sacrificial electron donors by adsorbing them onto an el

103 Instead of sacrificial electron donors, ferrocenes can be used as r

104 Ds as photosensitizer and ascorbic acid as a sacrificial electron source under visible light irradiat

105 complex is exposed to a large excess of the sacrificial electron-acceptor ceric ammonium nitrate at

106 uced all of the way to NH3 using protons and sacrificial electrons in aqueous solution.

107 d reduction of water assisted by appropriate sacrificial elements.

108 ) via atomic layer deposition (ALD) assisted sacrificial etching.

109 based on the rapid in situ dissolution of a sacrificial Fe(0) anode to generate iron precipitates wi

110 ssay is based on the displacement of a short sacrificial fluorescent-tagged indicator oligomer by a l

111 fluid-filled cavities were synthesized by a sacrificial galvanic replacement method.

112 oxide films during thermal oxidation of the sacrificial graphene template.

113 In aqueous electrolyte with a sacrificial hole acceptor (SO3(2-)), photoelectrodes sho

114 Pt tip and photocatalysis in the presence of sacrificial hole acceptors.

115 Here, we present a biofunctional sacrificial hydrogel coating for microfluidic chips that

116 Integration with a batch release of sacrificial hydrogel layers provides a high yield and th

117 ymers in integrated patterns and anchored on sacrificial hydrogels.

118 Alternatively, sacrificial hydrogen acceptors (e.g., tert-butylethylene

119 us metal catalysts, stoichiometric reagents, sacrificial hydrogen acceptors or high temperatures.

120 of alkanes (both with and without the use of sacrificial hydrogen acceptors).

121 Our results reveal mechanisms by which the sacrificial hydroxyl group on the chromanol group can tr

122 ted liquid (paraffin wax) that forms a solid sacrificial layer at room temperature.

123 The use of photoresist as the sacrificial layer facilitates the creation of long chann

124 Bovine serum albumin was selected as sacrificial layer for its well-known adhesion capabiliti

125 Once the sealing step is complete, the sacrificial layer is melted and removed, leaving enclose

126 The sacrificial layer technique is used to fabricate these d

127 ration were fabricated using silicon dioxide sacrificial layer techniques.

128 toresist (PR) template, where the PR acts as sacrificial layer to form wavelike arched structures.

129 te microfluidic chips, without the need of a sacrificial layer to prevent channel deformation, was us

130 Paraffin wax was used as a phase-changing sacrificial layer to protect microstructures during solv

131 first filled with water that formed a solid sacrificial layer when frozen.

132 ng a porous poly(methyl methacrylate) (PMMA) sacrificial layer, which creates a space between the hol

133 isms to either remove sulfate crusts or form sacrificial layers of calcite that consolidate mineral s

134 Our results demonstrate that sacrificial layers with solvent bonding can be implement

135 th microfluidic systems using phase-changing sacrificial layers.

136 The sacrificial material prevents the bonding solvent (aceto

137 ies formed by plates partially composed of a sacrificial material, a subsequent etching step furnishe

138 cile and capping agent free strategy using a sacrificial mesoporous silica (mSiO2) shell.

139 n acidic electrolyte, the rational design of sacrificial metal-organic frameworks toward this applica

140 a geometrically complex device, we first use sacrificial molding of a freeform 3D printed template to

141 e fluorescence imaging, we demonstrate these sacrificial nanofluidic chips can function to controllab

142 tional silica colloids onto Au surfaces as a sacrificial nanopatterning template.

143 Injection of small sacrificial NCs (SNCs) as shell precursors into larger c

144 Noncovalent interactions are used as a sacrificial network to toughen covalently crosslinked hy

145 Photolithography defines the position of a sacrificial nickel nanoband electrode, which is recessed

146 It has been suggested that DNA contains sacrificial nucleobase sequences that protect sensitive

147 s in the detailed instructions given for the sacrificial offering of animals at the altar.

148 e for purification ceremonies at the Temple, sacrificial offerings were made subsequently in seeking

149 the presence of stoichiometric quantities of sacrificial olefin, which is hydrogenated to consume the

150 Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the pall

151 ppmcn)Cl2 (1), to WO3 removes the need for a sacrificial oxidant and increases the rate of photoelect

152 and 14(out)-Mn(III)-1 in the presence of the sacrificial oxidant iodosylarene.

153 action catalyzed by gold in the absence of a sacrificial oxidant is described.

154 colloidal CdS quantum dots (QDs), without a sacrificial oxidant or reductant, and without a co-catal

155 ome drug development and albumin as a novel, sacrificial oxidant scavenging protein in parasite redox

156 on of water to dioxygen in the presence of a sacrificial oxidant.

157 gen serves as the terminal oxidant, or cheap sacrificial oxidants are used, providing a very practica

158 y function in the dark and therefore require sacrificial oxidants such as Ce(4+) or S2O8(2-) to provi

159 are found to be promising photocatalysts for sacrificial photocatalytic hydrogen evolution with a max

160 We present evidence for Cp* being a sacrificial placeholder ligand in the [Cp*Ir(III)(chelat

161 Increasing the initial fraction of sacrificial poly(ethylene oxide) fibers enhanced cell in

162 oly(epsilon-caprolactone) and water-soluble, sacrificial poly(ethylene oxide), which can be selective

163 lline boundaries, and the composition of the sacrificial polycrystalline layer establishes the chemis

164 -oxoG), which serves as a proxy for possibly sacrificial protective low oxidation potential sites, wa

165 phloroglucinol) was assessed by competitive sacrificial reactions with 4-methyl-1,2-benzoquinone, qu

166 enzyme that uses methanethiol as an external sacrificial reagent to repair DNA methyl phosphotriester

167 the production of hydrogen with the use of a sacrificial reagent.

168 r oxygen via a low-energy pathway needing no sacrificial reagent.

169 litting) without the use of external bias or sacrificial reagents is of particular interest because o

170 of H2O, can potentially be performed without sacrificial reagents.

171 PCET in artificial molecular systems without sacrificial reagents.

172 ight irradiation without any co-catalysts or sacrificial reagents.

173 heme cleavage, because it does not require a sacrificial reducing agent to initiate the process.

174 ar catalyst, and triethanolamine (TEOA) as a sacrificial reducing agent.

175 tosensitizer and triethanolamine (TEOA) as a sacrificial reducing agent.

176 [(Mes)2 P]Li, the latter of which acts as a sacrificial reducing agent.

177 tivate the molecular oxygen; in our case, no sacrificial reductant is needed.

178 ([Co(bpy)(3)]Cl(2)), and triethanolamine (a sacrificial reductant) with ultra-bright light emitting

179 t, for each step in the catalytic cycle, the sacrificial reductant, 3-mercaptopropionic acid, scaveng

180 uction catalyst, KCl, and ascorbic acid as a sacrificial reductant, using visible light irradiation a

181 Detection employs tripropylamine, a sacrificial reductant, while applying 0.95 V vs Ag/AgCl.

182 ed photochemically using ethanol (EtOH) as a sacrificial reductant.

183 s notably and on the other hand it acts as a sacrificial reductant.

184 he cathode resides in a channel containing a sacrificial reductant.

185 iment, deplete molecular oxygen as long as a sacrificial reduction component is present in excess con

186 rsibly oxidized or can instead function as a sacrificial regulator.

187 Whether even earlier "sacrificial" reinfusion of approximately 2 x 10(8)/kg un

188 ally fluid, low-defect lipid layers serve as sacrificial resists for the deposition of protein and ot

189 ent this inherent trade-off by incorporating sacrificial, reversible iron-catechol cross-links into a

190 Such a sacrificial role for an iron-sulfur cluster during catal

191 in formation is consistent with the proposed sacrificial S-donating function of the [2Fe-2S] cluster

192 s a possible role of the second cluster as a sacrificial S-donor in the MiaB-catalyzed reaction.

193 After selective chemical etching of sacrificial segments, structures with gaps as small as 2

194 For lower Rh content, sacrificial self-stabilization of individual nanoparticl

195 The sacrificial shell protects the core layer with the drugs

196 rocesses, this strategy extracts a patterned sacrificial silicon layer through hundreds of millions o

197 Lateral electrochemical undergrowth of a sacrificial SiO x layer was achieved by photoelectrochem

198 inting strategy was employed by generating a sacrificial spacer through the reaction of two 3-isocyan

199 alysis) of methylene blue chromophore with a sacrificial sterically hindered amine reductant and an o

200 ctronics or enable the direct writing of the sacrificial structures for nanoscale lithography.

201 rays of gate stacks are first patterned on a sacrificial substrate, and then transferred onto arbitra

202 orted PdxBi catalysts are synthesized by the sacrificial support method.

203 were directly grown on stainless steel via a sacrificial template accelerated hydrolysis and post cal

204 ocrystal cores with a layer of Cu(2)O as the sacrificial template and then a layer of polycrystalline

205 The sacrificial template contained known amounts of Tb and T

206 substrate for loading active materials, 2) a sacrificial template for creating hollow tubular structu

207 ute based on porous tellurium nanotubes as a sacrificial template for hierarchically porous 1D carbon

208 a breath figure array of droplets, forming a sacrificial template for the drying polymer film.

209 The use of dextran as a sacrificial template for the fabrication of metallic and

210 Subsequent removal of the sacrificial template gave an open vesicular structure.

211 ate glass, and used them as a cytocompatible sacrificial template in engineered tissues containing li

212 ut it transforms to yolk-shell, with neither sacrificial template nor core etching, because of geomet

213 use of colloidal polystyrene microbeads as a sacrificial template to create a nanofibrous network coa

214 oxide both as support to load MNPs and as a sacrificial template to grow MOFs.

215 Herein, we develop an electrochemical sacrificial-template strategy to fabricate hollow Co3 O4

216 cs, data storage, optoelectronics, displays, sacrificial templates and all forms of sensors.

217 micro-sized oxides, and their application as sacrificial templates for morphology-controlled synthesi

218 The Ag nanocubes can then serve as sacrificial templates for the preparation of Au nanocage

219 th structural hierarchy, but the use of soft sacrificial templates in the synthesis of metallic spong

220 ighly ordered nanopillars without the use of sacrificial templates or any expensive equipment.

221 d nanopores in solution without the need for sacrificial templates or postsynthesis processing is rep

222 The silver cubes could serve as sacrificial templates to generate single-crystalline nan

223 pensive lithography techniques or the use of sacrificial templates with sophisticated growth and proc

224 templating (mesoporous silicas or carbons as sacrificial templates), colloidal crystal templating (3-

225 ntrol of hollow NPs beyond the morphology of sacrificial templates, but also expands our understandin

226 the catalyst particles with single-molecule sacrificial templates, then partially overcoating the ca

227 sules, the colloidal particle deposition on (sacrificial) templates, the amphiphilicity driven self-a

228 A sacrificial templating process using lithographically pr

229 s cacao use as part of a mortuary ritual for sacrificial victims, an event that occurred during the h

230 ty relationships will help identifying novel sacrificial ZIF or porous metal-organic frameworks leadi