ライフサイエンスコーパス: sulfuryl

1 ical olefin-addition reactions with bromine, sulfuryl chloride, m-chloroperbenzoic acid, dioxygen, an

2 nly used S(VI) electrophiles, and the parent sulfuryl chloride, O2 S(VI) Cl2 , has also been relied o

3 heteroarenes in good yield by treatment with sulfuryl diimidazole in nonpolar solvents at elevated te

4 PAPS serves as the sulfuryl donor for the biosynthesis of all sulfate ester

5 CoA that was competitive with respect to the sulfuryl donor substrate, 3'-phosphoadenosine-5'-phospho

6 constants for hydrolysis of a wide range of sulfuryl esters, ArOSO(2)X(-), are shown to be correlate

7 od for the deoxyfluorination of phenols with sulfuryl fluoride (SO2F2) and tetramethylammonium fluori

8 etramethylammonium 2,6-dimethylphenoxide and sulfuryl fluoride (SO2F2) serves as a particularly pract

9 This enzyme transfers the sulfuryl group (SO(3)) from 3'-phosphoadenosine 5'-phosp

10 density of this oxygen atom on a transferred sulfuryl group accounts for a large fraction of the decr

11 The universal sulfuryl group donor for SULT-catalyzed sulfation is ade

12 The universal sulfuryl group donor for SULTcatalyzed sulfation is aden

13 In mammals, the universal sulfuryl group donor molecule 3'-phosphoadenosine 5'-pho

14 gi enzymes that catalyze the transfer of the sulfuryl group from 3'-phosphoadenosine 5'-phosphosulfat

15 nsferase (EST) catalyzes the transfer of the sulfuryl group from 3'-phosphoadenosine 5'-phosphosulfat

16 roup of enzymes catalysing the transfer of a sulfuryl group from 3'-phosphoadenosine 5'-phosphosulpha

17 Sulfotransferases catalyze the transfer of a sulfuryl group from the eukaryotic sulfate donor 3'-phos

18 phoadenosine 5'-phosphosulfate (PAPS), whose sulfuryl group is reduced or transferred to other metabo

19 ansferase (EST) catalyzes transfer of the 5'-sulfuryl group of adenosine 3'-phosphate 5'-phosphosulfa

20 S/MS) analysis under conditions in which the sulfuryl group of sulfotyrosine is labile.

21 Receipt of the sulfuryl group often radically alters acceptor-target in

22 isotope effects support the notion that the sulfuryl group resembles SO(3) in the transition state.

23 s of enzymes that catalyze the transfer of a sulfuryl group to a hydroxyl or amine moiety on various

24 -3), a key sulfotransferase that transfers a sulfuryl group to a specific glucosamine in HS generatin

25 directions indicates that the transfer of a sulfuryl group to an aryl hydroxyl group catalyzed by be

26 NodST catalyzes the sulfuryl group transfer from 3'-phosphoadenosine 5'-phos

27 ohydrate sulfotransferase Stf0 catalyzes the sulfuryl group transfer from 3'-phosphoadenosine-5'-phos

28 measured, and the catalytic mechanism of the sulfuryl group transfer reaction was investigated in ini

29 Arg78 is in close proximity to the site of sulfuryl group transfer.

30 tem since no shift in absorption accompanies sulfuryl group transfer.

31 catalytic histidine residue, (2) an in-line sulfuryl-group transfer mechanism, and (3) constraints i

32 rases in liver and catalyzes transfer of the sulfuryl moiety (-SO(3)) from activated sulfate (PAPS, 3

33 solic sulfotransferases (SULTs) transfer the sulfuryl moiety (-SO(3)) from activated sulfate [3'-phos

34 ysiological relevance by the transfer of the sulfuryl moiety (-SO(3)) from PAPS (3'-phosphoadenosine

35 ignaling small molecules via transfer of the sulfuryl moiety (-SO3) from 3'-phosphoadenosine 5'-phosp

36 of signaling metabolites via transfer of the sulfuryl moiety (-SO3) from activated sulfate (3'-phosph

37 s and other xenobiotics--by transferring the sulfuryl moiety (SO3) from 3'-phosphoadenosine 5'-phosph

38 ults show that while the interactions of the sulfuryl moiety and the phenyl ring with the YopH active

39 network with the hydroxyl group ortho to the sulfuryl moiety, which may be exploited to design more p

40 switched "on" and "off" via transfer of the sulfuryl-moiety (-SO3) from PAPS (3'-phosphoadenosine 5'

41 ll kinetic isotope effect in the nonbridging sulfuryl oxygen atoms suggests no significant change in

42 for the estrogen sulfotransferase-catalyzed sulfuryl (SO3) transfer from p-nitrophenyl sulfate to th

43 faster than the aqueous reaction, while the sulfuryl transfer from the pNPS anion is some 40-fold sl

44 Understanding phosphoryl and sulfuryl transfer is central to many biochemical process

45 istic of the transition state for an in-line sulfuryl transfer reaction from PAPS to E2.

46 in position to play a catalytic role in the sulfuryl transfer reaction of EST.

47 Sulfuryl transfer reactions of sulfate diesters (RO-SO(2

48 on of the data for enzymatic and uncatalyzed sulfuryl transfer reactions suggests that both proceed t

49 del systems for understanding phosphoryl and sulfuryl transfer reactions, respectively.

50 ups are aryl groups the hydrolysis reaction (sulfuryl transfer to water) occurs by way of attack at s

51 PAPS and K(I) values for PAP, the product of sulfuryl transfer.

52 at can be used to regulate specific areas of sulfuryl-transfer metabolism.

53 echanistic similarities, the phosphoryl- and sulfuryl-transfer reactions differ markedly in their res

54 ts and medium effects have been measured for sulfuryl-transfer reactions of the sulfate ester p-nitro